An eigenvalue is how much it is scaled. For example, if a vector $\begin{bmatrix}2 \\ 3\end{bmatrix}$ becomes $\begin{bmatrix}3 \\ 2\end{bmatrix}$ after a transformation, it's not an eigenvector. However, if it becomes $\begin{bmatrix}-4 \\ -6\end{bmatrix}$, it is an eigenvector, and its eigenvalue is -2.
Formal Definition
Note- $\vec{0}$ is never an eigenvector, because that works for every possible matrix.
Finding Eigenvectors and Eigenvalues
We're going to dedicate an entire post to calculating eigenvalues and eigenvectors, for now it's important to know this:
Theorem: Triangular Matrix
The eigenvalues of a triangular matrix are the entries on its main diagonal.
Proof
Theorem 2: Eigenvectors corresponding to distinct eigenvalues are linearly independent
Application
This lets us construct vectors as linear combinations of eigenvectors, which lets us calculate matrix multiplication really easily.